Thermodynamics for Chemical Engineers (2)

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About Course

Thermodynamics 2 considers some differential mathematics, working with solutions and mixtures, fugacity, vapour-liquid equilibrium and chemical reaction equilibrium. Much consideration is given to what to do when our components are real or ideal under the given conditions. When it comes to mixtures, we consider whether the mixtures themselves are also ideal or real mixtures.

It is a very interesting course with a lot to learn. Attached to the course are files that contain various tables and graphs. Relevant materials will be attached to each lesson as well.

Special thanks to Tracy Nyame, Rachael Pekwara Wassah and Amy Amudzi-Deku for their input. They helped in the preparation of some of the slides and this would have been more difficult to set up without them.

All the best in your thermodynamic journey…

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What Will You Learn?

  • Concepts on thermodynamic relations (looking into differential mathematics and the Maxwell relations), fugacity, vapour-liquid equilibrium, mixtures and solution thermodynamics and chemical reaction equilibrium.

Course Content

Introduction to thermodynamics II and thermodynamic relations

  • Introduction to thermodynamics II and differential relations
    23:27
  • Differential relations example
    15:54
  • Maxwell relations part 1
    15:59
  • Maxwell relations part 2
    12:10
  • Thermodynamic relations: Applications part 1
    14:54
  • Thermodynamic relations: Applications part 2
    11:45
  • Thermodynamic relations: Applications part 3
    06:08
  • Finite difference approximations
    18:41
  • Clapeyron and Clausius-Clapeyron equations
    30:28

PVT Behaviour of gases

(Enthalpy, Internal energy and Entropy) HUS Behaviour of gases

Fugacity

Thermodynamic Mixtures (liquids)
We discuss solution and mixture thermodynamics for mainly liquid systems

Gas Mixtures

Reaction Equilibria

MATLAB:Properties of Gas Mixtures
We use Matlab to solve some questions under the properties of gas mixtures

Thermo games

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